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«Danger: Causes serious eye damage. Harmful if inhaled. Suspected of causing cancer. May damage the unborn child. Suspected of damaging fertility. ...»

-- [ Page 1 ] --

Cauldron ®

A broad spectrum fungicide for use in winter wheat, spring wheat, winter barley, spring barley, oats,

rye and triticale.

An oil dispersion containing 140 g/litre (13.4% w/w)

boscalid and 50 g/litre (4.8% w/w) epoxiconazole.

Danger:

Causes serious eye damage.

Harmful if inhaled.

Suspected of causing cancer.

May damage the unborn child. Suspected of damaging fertility.

Very toxic to aquatic life with long lasting effects.

Wear protective gloves/clothing/eye protection.

ection.

Use only outdoors or in a well-ventilated area.

Immediately call a POISON CENTRE or doctor/physician.

IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

Store locked up.

Dispose of contents/container to a licensed waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste.

To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies.

PCS No. 03971 5L℮ To avoid risks to human health and the environment, comply with the instructions for use.

UN 3082 Environmentally Hazardous substance, liquid, N.O.S.

(contains boscalid, epoxiconazole) Marine pollutant

Supplied by: Authorization holder:

BASF Ireland Limited BASF plc, P O Box 4, 81086233IE1044 P.O.

Box 4, Earl Road Earl Road, Cheadle Hulme, Cheadle Hulme, CHEADLE Cheshire, SK8 6QG, UK Cheshire SK8 6QG, UK Tel: 01 825 5701 Fax: 01 825 2038 Emergency Information (24 hours freephone):

Technical Enquiries:

0044 (0)845 602 2553 (office hours) ® = Registered trademark of BASF

FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE, as directed below:

Crops Maximum Individual Maximum total Latest time of application dose dose Wheat (winter) 2.5 litres product/ha 5 litres product/ha Before watery ripe Wheat (spring) stage (GS 71) Rye Triticale Barley (winter) 2.5 litres product/ha 5 litres product/ha Before beginning Barley (spring) of flowering (GS 61) Oats

READ ALL PRECAUTIONS BEFORE USE

PRECAUTIONS

WEAR SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when

handling the concentrate.

WEAR SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces.

IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible).

WHEN USING DO NOT EAT, DRINK OR SMOKE.

WASH HANDS AND EXPOSED SKIN before meals and after work.

KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.

KEEP OUT OF REACH OF CHILDREN.

VERY TOXIC TO AQUATIC ORGANISMS, may cause long-term adverse effects in the aquatic environment. Do not contaminate surface waters or ditches with chemical or used container.

Do not contaminate water with the product or its container. (Do not clean application equipment near surface water / Avoid contamination via drains from farmyards and roads).

To protect aquatic organisms respect an unsprayed buffer zone of 5m to surface water bodies.

KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.

RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of safely.

STORAGE

Store in a suitable pesticide store, keep dry and protect from frost.

SHAKE WELL BEFORE USE.

DIRECTIONS FOR USE

IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.

Cauldron is a broad spectrum fungicide with systemic, protectant and curative properties for use in winter wheat, spring wheat, winter barley, spring barley, oats, rye and triticale.

1. Restrictions/Warnings For professional use only.

Avoid spray drift on to neighbouring crops.

Effects on baking and brewing have not been fully tested. Consult the grain merchant or processor before use.

This product may cause damage to broad-leaved plant species.

Wash equipment thoroughly after use.

–  –  –

Resistance Use Cauldron as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate other fungicides with a different mode of action.

Cauldron contains epoxiconazole, a DMI fungicide. Resistance to some DMI fungicides has been identified in Septoria leaf blotch (Mycosphaerella graminicola) which may seriously affect the performance of some products. For further advice on resistance management in DMIs contact your agronomist or specialist advisor, and visit the FRAG-UK website.

Cauldron contains boscalid which belongs to the SDHI (carboxamide) group of fungicides. To minimise the risk of resistance occurring, apply a maximum of two SDHI fungicide sprays per cereal crop.





3. Crops Cauldron is a broad spectrum fungicide with systemic, protectant and curative properties for use in winter wheat, spring wheat, winter barley, spring barley, oats, rye and triticale for disease control as summarised below.

Time of Application Apply Cauldron at the start of foliar or stem based disease attack. A maximum of two applications can be made before watery ripe stage (GS 71) in winter and spring wheat, rye and triticale, and before beginning of flowering (GS 61) in winter and spring barley and oats.

Rate of Application Apply 2.5 litres Cauldron in a minimum of 200 litres of water per hectare.

Qualified recommendation Cauldron may be applied at 2.5 litres per hectare in 100 litres of water per hectare although efficacy at this reduced volume has not been evaluated. Therefore application at 100 litres water per hectare is at user’s risk with regard to biological efficacy.

4. Following crops After treating a cereal crop with Cauldron, onions, oats, sugar beet, oilseed rape, cabbages, carrots, sunflowers, barley, lettuce, ryegrass, dwarf French beans, peas, potatoes, clover, wheat, field beans and maize may be sown as the following crop.

5. Mixing and Spraying For use by tractor mounted/trailed sprayer only.

Half fill the spray tank with clean water and start the agitation. SHAKE THE CONTAINER WELL before use and pour in the required amount of product. Rinse any empty containers thoroughly and add rinsings to the spray tank. Add the remainder of the water and continue agitation until spraying is completed.

On emptying the container, rinse container thoroughly by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of container safely.

The following does not form part of the product label under S.I. No.159 of 2012:

With many products there is a general risk of resistance developing to the active ingredients.

For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

CAULDRON

1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: crop protection product, fungicide

1.3. Details of the supplier of the safety data sheet

Company:

BASF SE

67056 Ludwigshafen

GERMANY

Contact address:

BASF plc PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire SK8 6QG, UNITED KINGDOM Telephone: +44 161 485-6222 E-mail address: product-safety-north@basf.com

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

–  –  –

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures Do not breathe vapour/spray. Use personal protective clothing. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.

Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters.

Keep people and animals away.

6.3. Methods and material for containment and cleaning up For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

For large amounts: Dike spillage. Pump off product.

Wear suitable protective equipment. Dispose of absorbed material in accordance with regulations.

Collect waste in suitable containers, which can be labelled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.

6.4. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Remove contaminated clothing and protective equipment before entering eating areas.

Protection against fire and explosion:

Vapours may form ignitable mixture with air. Prevent electrostatic charge – sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds.

Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters Components with occupational exposure limits none Refer to the current schedule of occupational exposure standards published by the Irish HSA. For normal use and handling refer to the product label/leaflet. In all other cases the following apply.

133855-98-8: Epoxiconazole; (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1yl)methyl]oxirane TWA value 0.3 mg/m3 (Recommendation of BASF), Respirable dust

8.2. Exposure controls Personal protective equipment

Respiratory protection:

Suitable respiratory protection for lower concentrations or short-term effect: Combination filter for gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN 14387 Type ABEK-P3)

Hand protection:

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended:

Protective index 6, corresponding 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures The statements on personal protective equipment in the instructions for use apply when handling cropprotection agents in final-consumer packing. Wearing of closed work clothing is recommended. Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties Form: dispersion Colour: white Odour: faintly aromatic Odour threshold: Not determined since harmful by inhalation.

pH value: approx. 3 – 5 (pH Meter) (CIPAC standard water D, 1 %(m), 20 °C) Melting point: approx. -23 °C Information applies to the solvent.

Boiling point: approx. 246 °C Information applies to the solvent.



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